Hệ PT : 80x + 223b= 3,83

x+ y= nO trong oxit =0,84/28=0,03

=> x=0,02 y=0,01

=> mCuO=1,6 g

m PbO=2,23 g

Đặt : x là n_CuO ; y là n_PbO

\(n_{CO}=\frac{0,84}{28}=0,03\left(mol\right)\)

\(CuO+CO-^{t^o}\rightarrow Cu+CO_2\)

x..............x............

\(PbO+CO-^{t^o}\rightarrow Pb+CO_2\)

y............y,................

Theo đề bài ta có hệ : \(\left\{{}\begin{matrix}80x+223y=3,83\\x+y=0,03\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}m_{CuO}=0,02.80=1,6\left(g\right)\\m_{PbO}=0,01.223=2,23\left(g\right)\end{matrix}\right.\)

Học tốt nha!

CuO+CO-->Cu+CO2

PbO+CO-->Pb+CO2

GỌI x là nCuO ,ylà nPbO

Hệ PT : 80x + 223b= 3,83

x+ y= nO trong oxit =0,84/28=0,03

=> x=0,02 y=0,01

=> mCuO=1,6 g

m PbO=2,23 g

a: \(C+O_2\rightarrow CO_2\)(ĐK: t độ)

x         x          x

\(S+O_2\rightarrow SO_2\)(ĐK: t độ)

y       y         y

b: \(n_{O_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)

Theo đề, ta có hệ:

12x+32y=10 và x+y=0,5

=>x=0,3 và y=0,2

\(m_C=0.3\cdot12=3.6\left(g\right)\)

\(m_S=0.2\cdot32=6.4\left(g\right)\)

c: \(n_{CO_2}=n_C=0.3\left(mol\right)\)

\(n_{SO_2}=n_S=0.2\left(mol\right)\)

\(V_{khí}=22.4\left(0.3+0.2\right)=11.2\left(lít\right)\)

\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH :

\(C+O_2\rightarrow\left(t^o\right)CO_2\)

x       x               x 

\(S+O_2\rightarrow\left(t^o\right)SO_2\)

y      y                y

Gọi n C = x 

     n S = y (mol)

Ta có hệ PT :

\(\left\{{}\begin{matrix}12x+32y=10\\x+y=0,5\end{matrix}\right.\)

\(\rightarrow x=0,3;y=0,2\)

\(m_C=0,3.12=3,6\left(g\right)\)

\(m_S=0,2.32=6,4\left(g\right)\)

\(c,V_{hhk}=\left(0,3+0,2\right).22,4=11,2\left(l\right)\)

_Nung nóng hỗn hợp gồm CuO và PbO bằng C: 
Gọi a,b là số mol của CuO và PbO: 
=>80a+223b=19.15(1) 
2CuO+C(t*)=>2Cu+CO2 
a------->0.5a--->a--->0.5a(mol) 
2PbO+C(t*)=>2Pb+CO2 
b------>0.5b---->b---->0.5b(mol) 
_Cho CO2 sản phẩm vào dd Ca(OH)2 thu được kết tủa trắng CaCO3: 
+nCaCO3=7.5/100=0.075(mol) 
CO2+Ca(OH)2=>CaCO3+H2O 
0.075---------------->0.075(mol) 
=>0.5a+0.5b=0.075(2) 
Từ(1)(2)=>a=0.1,b=0.05 
=>mCuO=0.1*80=8(g) 
=>mPbO=0.05*223=11.15(g) 
+nCu=0.1(mol) 
=>mCu=0.1*64=6.4(g) 
+nPb=0.05(mol) 
=>mPb=0.05*207=10.35(g) 
=>m(KL)=6.4+10.35=16.75(g) 

c) 
+nC=0.5(a+b)=0.5(0.1+0.05)=0.075(mol) 
=>mC=0.075*12=0.9(g)

\(n_{Pb}=\dfrac{2,07}{207}=0,01mol\)

\(n_{Cu}=\dfrac{1,6}{64}=0,025mol\)

\(PbO+H_2\rightarrow\left(t^o\right)Pb+H_2O\)

0,01    0,01            0,01            ( mol )

\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)

0,025  0,025        0,025            ( mol )

\(m_{hh}=m_{PbO}+m_{CuO}=\left(0,01.223\right)+\left(0,025.80\right)=4,23g\)

\(V_{H_2}=\left(0,01+0,025\right).22,4=0,784l\)

\(n_{Pb}=\dfrac{2,07}{207}=0,01\left(mol\right)\\ n_{Cu}=\dfrac{1,6}{64}=0,025\left(mol\right)\\ PTHH:PbO+H_2\underrightarrow{t^o}Pb+H_2O\\ Mol:0,01\leftarrow0,01\leftarrow0,01\\ CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Mol:0,025\leftarrow0,025\leftarrow0,025\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,025.80=2\left(g\right)\\m_{PbO}=0,01.223=2,23\left(g\right)\end{matrix}\right.\Rightarrow m_{oxit}=2+2,23=4,23\left(g\right)\\ V_{H_2}=\left(0,01+0,025\right).22,4=0,784\left(l\right)\)

PTHH: \(C+O_2\xrightarrow[]{t^o}CO_2\)

              a___a______a    (mol)

            \(S+O_2\xrightarrow[]{t^o}SO_2\)

             b___b_______b   (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}12a+32b=10\\a+b=\dfrac{11,2}{22,4}=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,3\\b=0,2\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_C=0,3\cdot12=3,6\left(g\right)\\m_S=6,4\left(g\right)\\V_{khí}=0,5\cdot22,4=11,2\left(l\right)\end{matrix}\right.\)

\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{CO_2}=n_{CaCO_3}=\dfrac{25}{100}=0,25\left(mol\right)\\ PTHH:CO+CuO\rightarrow\left(t^o\right)Cu+CO_2\\ n_{CO}=n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\\ V_{hh\left(đktc\right)}=\left(n_{CO}+n_{CO_2}\right).22,4=\left(0,5+0,25\right).22,4=16,8\left(l\right)\)

\(2CO + O_2 \xrightarrow{t^o} 2CO_2\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{CO} = n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{n_{CO} + n_{H_2}}{2}=\dfrac{0,2+n_{H_2}}{2} = \dfrac{9,6}{32} = 0,3(mol)\\ \Rightarrow n_{H_2} = 0,4(mol)\\ \%V_{CO} = \dfrac{0,2}{0,2 + 0,4}.100\% = 33,33\%\\ \%V_{H_2} = 100\% - 33,33\% = 66,67\%\\ \%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\%=87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)

a, \(CuO+H_2\underrightarrow{^{t^o}}Cu+H_2O\)

\(Fe_2O_3+3H_2\underrightarrow{^{t^o}}2Fe+3H_2O\)

Gọi: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\) ⇒ 80x + 160y = 40 (1)

Theo PT: \(n_{H_2}=n_{CuO}+3n_{Fe_2O_3}=x+3y=\dfrac{13,44}{22,4}=0,6\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,3.80=24\left(g\right)\\m_{Fe_2O_3}=0,1.160=16\left(g\right)\end{matrix}\right.\)

b, \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{24}{40}.100\%=60\%\\\%m_{Fe_2O_3}=40\%\end{matrix}\right.\)